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Issue 22, 2014
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Peroxynitrite chemistry derived from nitric oxide reaction with a Cu(II)–OOH species and a copper mediated NO reductive coupling reaction

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Abstract

New peroxynitrite–copper chemistry ensues via addition of nitric oxide (˙NO(g)) to a CuII–hydroperoxo species. In characterizing the system, the ligand–Cu(I) complex was shown to effect a seldom observed ˙NO(g) reductive coupling reaction. Biological implications are discussed.

Graphical abstract: Peroxynitrite chemistry derived from nitric oxide reaction with a Cu(ii)–OOH species and a copper mediated NO reductive coupling reaction

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The article was received on 15 Oct 2013, accepted on 27 Nov 2013 and first published on 09 Dec 2013


Article type: Communication
DOI: 10.1039/C3CC47942K
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Citation: Chem. Commun., 2014,50, 2844-2846
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    Peroxynitrite chemistry derived from nitric oxide reaction with a Cu(II)–OOH species and a copper mediated NO reductive coupling reaction

    S. Kim, M. A. Siegler and K. D. Karlin, Chem. Commun., 2014, 50, 2844
    DOI: 10.1039/C3CC47942K

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