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Issue 3, 2014
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Imine hydrogenation by alkylaluminum catalysts

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Abstract

Di-isobutylaluminum hydride and tri-iso-butylaluminum (DIBAL 1, TIBAL 2) are shown to be efficient hydrogenation catalysts for a variety of imines at 100 °C and 100 atm of H2, operating via a hydroalumination/hydrogenolysis mechanism.

Graphical abstract: Imine hydrogenation by alkylaluminum catalysts

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Publication details

The article was received on 14 Oct 2013, accepted on 08 Nov 2013 and first published on 11 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC47889K
Citation: Chem. Commun., 2014,50, 301-303
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    Imine hydrogenation by alkylaluminum catalysts

    J. A. Hatnean, J. W. Thomson, P. A. Chase and D. W. Stephan, Chem. Commun., 2014, 50, 301
    DOI: 10.1039/C3CC47889K

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