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Issue 4, 2014
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Enhanced noble gas adsorption in Ag@MOF-74Ni

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Abstract

Various amounts of Ag nanoparticles were successfully deposited in porous MOF-74Ni (or Ni/DOBDC) by an auto-reduction method. An optimized silver-loaded MOF-74Ni was shown to have an improved Xe adsorption capacity (15% more) at STP compared to the MOF without silver nanoparticles. The silver-loaded sample also has a higher Xe/Kr selectivity. These results are explained by the stronger interactions between polarizable Xe molecules and the well-dispersed Ag nanoparticles.

Graphical abstract: Enhanced noble gas adsorption in Ag@MOF-74Ni

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Publication details

The article was received on 09 Oct 2013, accepted on 28 Oct 2013 and first published on 01 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC47777K
Citation: Chem. Commun., 2014,50, 466-468
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    Enhanced noble gas adsorption in Ag@MOF-74Ni

    J. Liu, D. M. Strachan and P. K. Thallapally, Chem. Commun., 2014, 50, 466
    DOI: 10.1039/C3CC47777K

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