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Issue 6, 2014
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Reactivity of a fac-ReCl(α-diimine)(CO)3 complex with an NAD+ model ligand toward CO2 reduction

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Abstract

The reactivity of a rhenium complex containing an NAD+ model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form of the complex and electrochemical CO2 reduction. The hydricity of the NADH-like complex was estimated by a thermodynamic cycle and reaction with Ph3C+.

Graphical abstract: Reactivity of a fac-ReCl(α-diimine)(CO)3 complex with an NAD+ model ligand toward CO2 reduction

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Publication details

The article was received on 07 Oct 2013, accepted on 05 Nov 2013 and first published on 06 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC47699E
Citation: Chem. Commun., 2014,50, 728-730
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    Reactivity of a fac-ReCl(α-diimine)(CO)3 complex with an NAD+ model ligand toward CO2 reduction

    Y. Matsubara, S. E. Hightower, J. Chen, D. C. Grills, D. E. Polyansky, J. T. Muckerman, K. Tanaka and E. Fujita, Chem. Commun., 2014, 50, 728
    DOI: 10.1039/C3CC47699E

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