Jump to main content
Jump to site search

Issue 4, 2014
Previous Article Next Article

From dense monomer salt crystals to CO2 selective microporous polyimides via solid-state polymerization

Author affiliations

Abstract

Fully aromatic polyimides are synthesized via solid-state polymerization of the corresponding monomer salts. The crystal structure of salts shows strong hydrogen bonding of the reactive groups and thereby paves the way for solid-state transformations. The polycondensation yields copies of the initial salt crystallite habits, accompanied by the development of a porosity especially suited for CO2.

Graphical abstract: From dense monomer salt crystals to CO2 selective microporous polyimides via solid-state polymerization

Back to tab navigation

Supplementary files

Publication details

The article was received on 06 Oct 2013, accepted on 29 Oct 2013 and first published on 19 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC47674J
Citation: Chem. Commun., 2014,50, 430-432
  •   Request permissions

    From dense monomer salt crystals to CO2 selective microporous polyimides via solid-state polymerization

    M. M. Unterlass, F. Emmerling, M. Antonietti and J. Weber, Chem. Commun., 2014, 50, 430
    DOI: 10.1039/C3CC47674J

Search articles by author

Spotlight

Advertisements