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Issue 40, 2014
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Spectroscopic characterization of a phenolate bound FeII–O2 adduct: gauging the relative “push” effect of a phenolate axial ligand

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Abstract

Dioxygen adducts of solvent, imidazole and phenolate bound iron porphyrin complexes are reported. The data show that the Fe–O vibration of the Fe–O2 species shifts from 584 cm−1 to 570 cm−1 as neutral axial ligands are replaced by the anionic phenolate ligand.

Graphical abstract: Spectroscopic characterization of a phenolate bound FeII–O2 adduct: gauging the relative “push” effect of a phenolate axial ligand

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Publication details

The article was received on 01 Oct 2013, accepted on 31 Oct 2013 and first published on 31 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC47528J
Citation: Chem. Commun., 2014,50, 5218-5220
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    Spectroscopic characterization of a phenolate bound FeII–O2 adduct: gauging the relative “push” effect of a phenolate axial ligand

    P. K. Das, K. Mittra and A. Dey, Chem. Commun., 2014, 50, 5218
    DOI: 10.1039/C3CC47528J

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