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Issue 40, 2014
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Negative area compressibility in silver(I) tricyanomethanide

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Abstract

The molecular framework Ag(tcm) (tcm = tricyanomethanide) expands continuously in two orthogonal directions under hydrostatic compression. The first of its kind, this negative area compressibility behaviour arises from the flattening of honeycomb-like layers during rapid pressure-driven collapse of the interlayer separation.

Graphical abstract: Negative area compressibility in silver(i) tricyanomethanide

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Publication details

The article was received on 13 Sep 2013, accepted on 09 Dec 2013 and first published on 09 Dec 2013


Article type: Communication
DOI: 10.1039/C3CC47032F
Citation: Chem. Commun., 2014,50, 5264-5266
  • Open access: Creative Commons BY license
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    Negative area compressibility in silver(I) tricyanomethanide

    S. A. Hodgson, J. Adamson, S. J. Hunt, M. J. Cliffe, A. B. Cairns, A. L. Thompson, M. G. Tucker, N. P. Funnell and A. L. Goodwin, Chem. Commun., 2014, 50, 5264
    DOI: 10.1039/C3CC47032F

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