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Issue 6, 2014
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Catalytic stereodivergent functionalization of H2@C60

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Abstract

A complete stereocontrol of 1,3-dipolar cycloaddition of N-metalated azomethine ylides onto endohedral fullerene H2@C60 is reported for the first time. The stereodivergent synthesis of either the cis or the trans endohedral cycloadduct is achieved with excellent diastereo- and enantioselectivities.

Graphical abstract: Catalytic stereodivergent functionalization of H2@C60

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Publication details

The article was received on 12 Sep 2013, accepted on 11 Nov 2013 and first published on 12 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC46999A
Citation: Chem. Commun., 2014,50, 740-742
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    Catalytic stereodivergent functionalization of H2@C60

    E. E. Maroto, M. Izquierdo, M. Murata, S. Filippone, K. Komatsu, Y. Murata and N. Martín, Chem. Commun., 2014, 50, 740
    DOI: 10.1039/C3CC46999A

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