Issue 6, 2014
From the journal:

Chemical Communications

Catalytic stereodivergent functionalization of H2@C60†

Enrique E. Maroto,a   Marta Izquierdo,a   Michihisa Murata,b   Salvatore Filippone,a   Koichi Komatsu,b   Yasujiro Murata*b  and  Nazario Martín*ac  

* Corresponding authors

a Departamento de Química Orgánica I, Facultad de Ciencias Químicas, Ciudad Universitaria, s/n 28040 Madrid, Spain
E-mail: nazmar@quim.ucm.es

b Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan
E-mail: yasujiro@scl.kyoto-u.ac.jp

c IMDEA - Nanociencia, Campus de la Universidad Autónoma de Madrid, 28049 Madrid, Spain

Abstract

A complete stereocontrol of 1,3-dipolar cycloaddition of N-metalated azomethine ylides onto endohedral fullerene H2@C60 is reported for the first time. The stereodivergent synthesis of either the cis or the trans endohedral cycloadduct is achieved with excellent diastereo- and enantioselectivities.

Graphical abstract: Catalytic stereodivergent functionalization of H2@C60

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Article information

DOI
https://doi.org/10.1039/C3CC46999A
Article type
Communication
Submitted
12 Sep 2013
Accepted
11 Nov 2013
First published
12 Nov 2013

Chem. Commun., 2014,50, 740-742

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Catalytic stereodivergent functionalization of H2@C60

E. E. Maroto, M. Izquierdo, M. Murata, S. Filippone, K. Komatsu, Y. Murata and N. Martín, Chem. Commun., 2014, 50, 740 DOI: 10.1039/C3CC46999A

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