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Issue 4, 2014
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Pd-catalyzed allylic alkylation of dienyl carbonates with nitromethane with high C-5 regioselectivity

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Abstract

A highly regioselective palladium-catalyzed allylic alkylation of dienyl esters with nitromethane has been developed, providing selective access to the C-5 attacked products. The structures of the ligands as well as the steric effect of the substrates are important factors in determining the regiochemical outcome of the reaction.

Graphical abstract: Pd-catalyzed allylic alkylation of dienyl carbonates with nitromethane with high C-5 regioselectivity

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Publication details

The article was received on 28 Aug 2013, accepted on 02 Nov 2013 and first published on 04 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC46574H
Citation: Chem. Commun., 2014,50, 484-486
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    Pd-catalyzed allylic alkylation of dienyl carbonates with nitromethane with high C-5 regioselectivity

    X. Yang, X. Li, C. Ding, C. Xu, L. Dai and X. Hou, Chem. Commun., 2014, 50, 484
    DOI: 10.1039/C3CC46574H

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