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Issue 6, 2014
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Palladium-catalyzed asymmetric 1,6-addition of diarylphosphines to α,β,γ,δ-unsaturated sulfonic esters: controlling regioselectivity by rational selection of electron-withdrawing groups

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Abstract

Palladium-catalyzed asymmetric 1,6-addition of diarylphosphines to electron-deficient dienes was developed through rational selection of electron-withdrawing groups on the dienes. Various chiral allylic phosphine derivatives were synthesized in good yields with high enantioselectivity (up to 96% ee).

Graphical abstract: Palladium-catalyzed asymmetric 1,6-addition of diarylphosphines to α,β,γ,δ-unsaturated sulfonic esters: controlling regioselectivity by rational selection of electron-withdrawing groups

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Publication details

The article was received on 16 Aug 2013, accepted on 10 Nov 2013 and first published on 11 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC46290K
Citation: Chem. Commun., 2014,50, 698-700
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    Palladium-catalyzed asymmetric 1,6-addition of diarylphosphines to α,β,γ,δ-unsaturated sulfonic esters: controlling regioselectivity by rational selection of electron-withdrawing groups

    J. Lu, J. Ye and W. Duan, Chem. Commun., 2014, 50, 698
    DOI: 10.1039/C3CC46290K

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