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Issue 3, 2014
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Investigations on the crystal plane effect of ceria on gold catalysis in the oxidative dehydrogenation of alcohols and amines in the liquid phase

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Abstract

Gold nanoparticles supported on ceria{110} crystal planes were more reactive than on ceria{111} and {100} in the oxidative dehydrogenation of alcohols. Kinetic analysis and a Hammett plot suggest that hydride transfer is involved, and the cationic gold is catalytically active.

Graphical abstract: Investigations on the crystal plane effect of ceria on gold catalysis in the oxidative dehydrogenation of alcohols and amines in the liquid phase

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The article was received on 13 Aug 2013, accepted on 28 Oct 2013 and first published on 28 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC46180G
Citation: Chem. Commun., 2014,50, 292-294
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    Investigations on the crystal plane effect of ceria on gold catalysis in the oxidative dehydrogenation of alcohols and amines in the liquid phase

    M. Wang, F. Wang, J. Ma, M. Li, Z. Zhang, Y. Wang, X. Zhang and J. Xu, Chem. Commun., 2014, 50, 292
    DOI: 10.1039/C3CC46180G

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