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Issue 1, 2014
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Stereoselective geminal difunctionalization of vinyl arenes mediated by the bromonium ion

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Abstract

An anti-Markovnikov geminal oxyamination of styrenyl alkenes in an intermolecular fashion using the umpolung strategy mediated by the bromonium ion is reported. Isotope labeling studies confirm the migration of the phenyl group in the semipinacol rearrangement.

Graphical abstract: Stereoselective geminal difunctionalization of vinyl arenes mediated by the bromonium ion

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Publication details

The article was received on 06 Aug 2013, accepted on 24 Oct 2013 and first published on 24 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC46003G
Citation: Chem. Commun., 2014,50, 70-72
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    Stereoselective geminal difunctionalization of vinyl arenes mediated by the bromonium ion

    P. V. Balaji and S. Chandrasekaran, Chem. Commun., 2014, 50, 70
    DOI: 10.1039/C3CC46003G

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