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Issue 7, 2014
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Co-assembly of a three-dimensional open framework sulfide with a novel linkage between an oxygen-encapsulated T3 cluster and a supertetrahedral T2 cluster

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Abstract

Solvothermal reactions of S, Ga and Sn using cis-2,6-dimethylmorpholine (DMMP) as an organic template, in the presence of a trace amount of H2O at 180 °C, generated microporous [C6H14NO]14.4[Ga6.40Sn21.60S52O8] material composed of hybrid T2 and T3 supertetrahedral clusters with a PtS type topology.

Graphical abstract: Co-assembly of a three-dimensional open framework sulfide with a novel linkage between an oxygen-encapsulated T3 cluster and a supertetrahedral T2 cluster

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Publication details

The article was received on 23 Jul 2013, accepted on 22 Oct 2013 and first published on 22 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC45439H
Citation: Chem. Commun., 2014,50, 796-798
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    Co-assembly of a three-dimensional open framework sulfide with a novel linkage between an oxygen-encapsulated T3 cluster and a supertetrahedral T2 cluster

    X. Han, Z. Wang, D. Liu, J. Xu, Y. Liu and C. Wang, Chem. Commun., 2014, 50, 796
    DOI: 10.1039/C3CC45439H

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