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Issue 7, 2014
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Double γ-alkylation of allylic phosphorus ylides: a unique access to oxa-bicyclic[3.3.0] diene skeletons

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Abstract

A new ylide-initiated tandem cyclization reaction based on γ-dialkylation of allylic ylides has been realized, delivering a series of [3.3.0] oxa-bicyclic dienes in high yields with perfect diastereoselectivity.

Graphical abstract: Double γ-alkylation of allylic phosphorus ylides: a unique access to oxa-bicyclic[3.3.0] diene skeletons

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Publication details

The article was received on 13 Jul 2013, accepted on 05 Nov 2013 and first published on 06 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC45286G
Citation: Chem. Commun., 2014,50, 808-810
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    Double γ-alkylation of allylic phosphorus ylides: a unique access to oxa-bicyclic[3.3.0] diene skeletons

    P. Wang, S. Liao, J. Zhu and Y. Tang, Chem. Commun., 2014, 50, 808
    DOI: 10.1039/C3CC45286G

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