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Issue 5, 2014
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Photocatalytic hydrogen production from a noble metal free system based on a water soluble porphyrin derivative and a cobaloxime catalyst

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Abstract

A combination of noble-metal free components, a water soluble porphyrin photosensitizer zinc meso-tetrakis(1-methylpyridinium-4-yl)porphyrin chloride [ZnTMPyP4+]Cl4 (1) with cobaloxime complex [CoIII(dmgH)2(py)Cl] (2) as a catalyst, creates an efficient system for photochemical hydrogen production acting under visible light with 280 TONs. This is the first example of a water soluble porphyrin acting as a photosensitizer for cobaloxime catalysed H2 production.

Graphical abstract: Photocatalytic hydrogen production from a noble metal free system based on a water soluble porphyrin derivative and a cobaloxime catalyst

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Publication details

The article was received on 04 Jul 2013, accepted on 17 Jul 2013 and first published on 22 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC45025B
Citation: Chem. Commun., 2014,50, 521-523
  • Open access: Creative Commons BY license
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    Photocatalytic hydrogen production from a noble metal free system based on a water soluble porphyrin derivative and a cobaloxime catalyst

    T. Lazarides, M. Delor, I. V. Sazanovich, T. M. McCormick, I. Georgakaki, G. Charalambidis, J. A. Weinstein and A. G. Coutsolelos, Chem. Commun., 2014, 50, 521
    DOI: 10.1039/C3CC45025B

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