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Issue 9, 2014
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Formation of the tetranuclear, tetrakis-terminal-imido Mn4IV(NtBu)8 cubane cluster by four-electron reductive elimination of tBuN[double bond, length as m-dash]NtBu. The role of the s-block ion in stabilization of high-oxidation state intermediates

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Abstract

Mn4IV3-NtBu)4(NtBu)4 is obtained from a previously reported asymmetric MnIV/V–Li–(NR)(N) cluster by the removal of Li from the starting cluster by ion metathesis, which triggers reductive elimination of azo-tert-butane to give a tetranuclear heterocubane cluster.

Graphical abstract: Formation of the tetranuclear, tetrakis-terminal-imido Mn4IV(NtBu)8 cubane cluster by four-electron reductive elimination of tBuN [[double bond, length as m-dash]] NtBu. The role of the s-block ion in stabilization of high-oxidation state intermediates

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Publication details

The article was received on 25 Mar 2013, accepted on 12 Nov 2013 and first published on 12 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC42165A
Citation: Chem. Commun., 2014,50, 1061-1063
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    Formation of the tetranuclear, tetrakis-terminal-imido Mn4IV(NtBu)8 cubane cluster by four-electron reductive elimination of tBuN[double bond, length as m-dash]NtBu. The role of the s-block ion in stabilization of high-oxidation state intermediates

    S. Vaddypally, S. K. Kondaveeti, J. H. Roudebush, R. J. Cava and M. J. Zdilla, Chem. Commun., 2014, 50, 1061
    DOI: 10.1039/C3CC42165A

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