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Formation of the tetranuclear, tetrakis-terminal-imido Mn4IV(NtBu)8 cubane cluster by four-electron reductive elimination of tBuN[double bond, length as m-dash]NtBu. The role of the s-block ion in stabilization of high-oxidation state intermediates

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a
Department of Chemistry, Temple University, 1901 N. 13th Street, Philadelphia, USA
E-mail: mzdilla@temple.edu ;
Tel: +1-215-204-7118
b
Department of Chemistry, Princeton University, Princeton, USA
Chem. Commun., 2014,50, 1061-1063

DOI: 10.1039/C3CC42165A
Received 25 Mar 2013, Accepted 12 Nov 2013
First published online 12 Nov 2013
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