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ortho-Selective nucleophilic addition of amines to 3-borylbenzynes: synthesis of multisubstituted anilines by the triple role of the boryl group

Akira Takagi,a   Takashi Ikawa,*ab   Kozumo Saito,a   Shigeaki Masuda,a   Toyohiro Itoa and   Shuji Akai*ab  
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a
School of Pharmaceutical Sciences, University of Shizuoka, 52-1, Yada, Suruga-ku, Shizuoka, Japan
b
Graduate School of Pharmaceutical Sciences, Osaka University, 1-6, Yamadaoka, Suita, Japan
E-mail: ikawa@phs.osaka-u.ac.jp, akai@phs.osaka-u.ac.jp;
Fax: +06-6879-8212 ;
Tel: +06-6879-8210
Org. Biomol. Chem., 2013,11, 8145-8150

DOI: 10.1039/C3OB41787E
Received 03 Aug 2013, Accepted 02 Oct 2013
First published online 02 Oct 2013
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