Jump to main content
Jump to site search

Issue 94, 2013
Previous Article Next Article

1,4-Metal migration in a Cp*Rh(III) complex

Author affiliations

Abstract

The reaction of [Cp*RhCl(Ph)(PR3)] (R = Ph or Me) with internal alkynes in the presence of NaBArF4 affords the o-vinylaryl complex with a Rh-(vinyl CH) agostic interaction by way of the alkyne insertion followed by 1,4-rhodium migration, providing the first example of the 1,4-migration of a Rh(III) center.

Graphical abstract: 1,4-Metal migration in a Cp*Rh(iii) complex

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 02 Sep 2013, accepted on 07 Oct 2013 and first published on 21 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC46700G
Citation: Chem. Commun., 2013,49, 11104-11106
  •   Request permissions

    1,4-Metal migration in a Cp*Rh(III) complex

    Y. Ikeda, K. Takano, S. Kodama and Y. Ishii, Chem. Commun., 2013, 49, 11104
    DOI: 10.1039/C3CC46700G

Search articles by author