Issue 94, 2013
From the journal:

Chemical Communications

1,4-Metal migration in a Cp*Rh(iii) complex†

Yousuke Ikeda,a   Koichi Takano,a   Shintaro Kodamaa  and  Youichi Ishii*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27 Kasuga, Bunkyo-ku, Tokyo, Japan
E-mail: yo-ishii@kc.chuo-u.ac.jp
Fax: +81-3-3817-1895
Tel: +81-3-3817-1901

Abstract

The reaction of [Cp*RhCl(Ph)(PR3)] (R = Ph or Me) with internal alkynes in the presence of NaBArF4 affords the o-vinylaryl complex with a Rh-(vinyl CH) agostic interaction by way of the alkyne insertion followed by 1,4-rhodium migration, providing the first example of the 1,4-migration of a Rh(III) center.

Graphical abstract: 1,4-Metal migration in a Cp*Rh(iii) complex

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Article information

DOI
https://doi.org/10.1039/C3CC46700G
Article type
Communication
Submitted
02 Sep 2013
Accepted
07 Oct 2013
First published
21 Oct 2013

Chem. Commun., 2013,49, 11104-11106

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1,4-Metal migration in a Cp*Rh(III) complex

Y. Ikeda, K. Takano, S. Kodama and Y. Ishii, Chem. Commun., 2013, 49, 11104 DOI: 10.1039/C3CC46700G

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