Issue 92, 2013
From the journal:

Chemical Communications

Z-Selective ring opening of vinyl oxetanes with dialkyl dithiophosphate nucleophiles†

B. Guoa  and  J. T. Njardarson*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, The University of Arizona, 1306 East University Blvd., Tucson, Arizona 85721, USA
E-mail: njardars@email.arizona.edu

Abstract

Dialkyl dithiophosphates selectively ring open vinyl oxetanes in excellent yields under mild reaction conditions to form useful allylic thiophosphate products with high Z-selectivity.

Graphical abstract: Z-Selective ring opening of vinyl oxetanes with dialkyl dithiophosphate nucleophiles

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Article information

DOI
https://doi.org/10.1039/C3CC46660D
Article type
Communication
Submitted
31 Aug 2013
Accepted
05 Oct 2013
First published
14 Oct 2013

Chem. Commun., 2013,49, 10802-10804

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Z-Selective ring opening of vinyl oxetanes with dialkyl dithiophosphate nucleophiles

B. Guo and J. T. Njardarson, Chem. Commun., 2013, 49, 10802 DOI: 10.1039/C3CC46660D

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