Jump to main content
Jump to site search

Issue 48, 2013
Previous Article Next Article

Simple synthesis of yolk-shelled ZnCo2O4 microspheres towards enhancing the electrochemical performance of lithium-ion batteries in conjunction with a sodium carboxymethyl cellulose binder

Author affiliations

Abstract

Mixed metal oxides have been attracting more and more attention recently because of their advantages and superiorities, which can improve the electrochemical performance of single metal oxides. These advantages include structural stability, good electronic conductivity, and reversible capacity. In this work, uniform yolk-shelled ZnCo2O4 microspheres were synthesized by pyrolysis of ZnCo-glycolate microsphere precursors which were prepared via a simple refluxing route without any precipitant or surfactant. The formation process of the yolk-shelled microsphere structure during the thermal decomposition of ZnCo-glycolate is discussed, which is mainly based on the heterogeneous contraction caused by non-equilibrium heat treatment. The performances of the as-prepared ZnCo2O4 electrodes using sodium carboxylmethyl cellulose (CMC) and poly-vinylidene fluoride (PVDF) as binders are also compared. Constant current and rate charge–discharge testing results demonstrated that the ZnCo2O4 electrodes using CMC as the binder had better performance than those using PVDF as the binder. It was worth pointing out that the electrode using CMC as the binder nicely yields a discharge capacity of 331 mA h g−1 after 500 cycles at a current density of 1000 mA g−1, which is close to the theoretical value of graphite (371 mA h g−1). Furthermore, the obtained synthetic insights on the complex hollow structures will be of benefit to the design of other anode materials for lithium ion batteries.

Graphical abstract: Simple synthesis of yolk-shelled ZnCo2O4 microspheres towards enhancing the electrochemical performance of lithium-ion batteries in conjunction with a sodium carboxymethyl cellulose binder

Back to tab navigation

Publication details

The article was received on 21 Sep 2013, accepted on 23 Oct 2013 and first published on 23 Oct 2013


Article type: Paper
DOI: 10.1039/C3TA13787B
Citation: J. Mater. Chem. A, 2013,1, 15292-15299
  •   Request permissions

    Simple synthesis of yolk-shelled ZnCo2O4 microspheres towards enhancing the electrochemical performance of lithium-ion batteries in conjunction with a sodium carboxymethyl cellulose binder

    J. Li, J. Wang, D. Wexler, D. Shi, J. Liang, H. Liu, S. Xiong and Y. Qian, J. Mater. Chem. A, 2013, 1, 15292
    DOI: 10.1039/C3TA13787B

Search articles by author

Spotlight

Advertisements