Issue 22, 2013
From the journal:

Journal of Materials Chemistry A

Dynamic Zn-based metal–organic framework: stepwise adsorption, hysteretic desorption and selective carbon dioxide uptake†

Bo Liu,a   Yuanpu Li,a   Lei Hou,a   Guoping Yang,a   Yao-Yu Wang*a  and  Qi-Zhen Shia  

* Corresponding authors

a Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University, Xi'an 710069, China
E-mail: wyaoyu@nwu.edu.cn
Tel: +86 29 88302604

Abstract

A new porous metal–organic framework based on paddle-wheel Zn2 units and an unsymmetrical pyridyl dicarboxylate, contains a 3D intersecting pore system with uncommon stepwise adsorption and hysteretic desorption behavior for N2, CO2 and H2 gases at low temperature, and shows high selectivity for CO2 over N2 at ambient temperature.

Graphical abstract: Dynamic Zn-based metal–organic framework: stepwise adsorption, hysteretic desorption and selective carbon dioxide uptake

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Article information

DOI
https://doi.org/10.1039/C3TA10918F
Article type
Communication
Submitted
05 Mar 2013
Accepted
05 Apr 2013
First published
05 Apr 2013

J. Mater. Chem. A, 2013,1, 6535-6538

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Dynamic Zn-based metal–organic framework: stepwise adsorption, hysteretic desorption and selective carbon dioxide uptake

B. Liu, Y. Li, L. Hou, G. Yang, Y. Wang and Q. Shi, J. Mater. Chem. A, 2013, 1, 6535 DOI: 10.1039/C3TA10918F

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