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Issue 22, 2013
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A new “zero-strain” material for electrochemical lithium insertion

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Abstract

A new “zero-strain” system, spinel Li1+xRh2O4, is found as an insertion material for lithium ions. A very small volume change of ca. 0.5% is observed in the two-phase reaction process. The “zero-strain” behavior is likely induced by itinerant t2g electrons with a suppressed Jahn–Teller effect.

Graphical abstract: A new “zero-strain” material for electrochemical lithium insertion

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Publication details

The article was received on 01 Mar 2013, accepted on 18 Apr 2013 and first published on 18 Apr 2013


Article type: Communication
DOI: 10.1039/C3TA10878C
Citation: J. Mater. Chem. A, 2013,1, 6550-6552
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    A new “zero-strain” material for electrochemical lithium insertion

    Y. Gu, K. Taniguchi, R. Tajima, S. Nishimura, D. Hashizume, A. Yamada and H. Takagi, J. Mater. Chem. A, 2013, 1, 6550
    DOI: 10.1039/C3TA10878C

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