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Issue 18, 2013
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Transmetalation: routes to metal exchange within metal–organic frameworks

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Abstract

The present work is a critical review of metal exchange (transmetalation) involving metal nodes and metalated struts in metal–organic frameworks. Particular emphasis is given to drawing parallels between different examples of transmetalation in order to understand the influence of coordination environment, solvents, nature of the metals and other variables on the process. We hope that the present review will be of use to those involved in the incorporation of various metal centers to create isostructural MOFs and study their properties.

Graphical abstract: Transmetalation: routes to metal exchange within metal–organic frameworks

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Publication details

The article was received on 23 Feb 2013, accepted on 20 Mar 2013 and first published on 21 Mar 2013


Article type: Feature Article
DOI: 10.1039/C3TA10784A
Citation: J. Mater. Chem. A, 2013,1, 5453-5468
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    Transmetalation: routes to metal exchange within metal–organic frameworks

    M. Lalonde, W. Bury, O. Karagiaridi, Z. Brown, J. T. Hupp and O. K. Farha, J. Mater. Chem. A, 2013, 1, 5453
    DOI: 10.1039/C3TA10784A

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