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Issue 11, 2013
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Fe2+-based layered porous coordination polymers and soft encapsulation of guests via redox activity

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Abstract

2-D layer type porous coordination polymers containing redox active Fe2+ centers were synthesized. One of the compounds [Fe(isophthalate)(4,4′-bipyridyl)] showed structural flexibility via guest adsorption, and we observed reversible Fe2+ and Fe3+ switching by iodine insertion. The composite showed electric conductivity.

Graphical abstract: Fe2+-based layered porous coordination polymers and soft encapsulation of guests via redox activity

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Publication details

The article was received on 07 Dec 2012, accepted on 18 Jan 2013 and first published on 21 Jan 2013


Article type: Paper
DOI: 10.1039/C3TA01414B
Citation: J. Mater. Chem. A, 2013,1, 3675-3679
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    Fe2+-based layered porous coordination polymers and soft encapsulation of guests via redox activity

    S. Horike, M. Sugimoto, K. Kongpatpanich, Y. Hijikata, M. Inukai, D. Umeyama, S. Kitao, M. Seto and S. Kitagawa, J. Mater. Chem. A, 2013, 1, 3675
    DOI: 10.1039/C3TA01414B

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