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Issue 3, 2013
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Stereoselective intramolecular cyclopropanation through catalytic olefin activation

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Abstract

A novel stereoselective and convergent catalytic method for the cyclopropanation of electron-neutral and -rich olefins by sulfonium ylides is reported which unusually proceeds through olefin activation rather than by metal carbene formation.

Graphical abstract: Stereoselective intramolecular cyclopropanation through catalytic olefin activation

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Publication details

The article was received on 05 Nov 2012, accepted on 03 Dec 2012 and first published on 04 Jan 2013


Article type: Edge Article
DOI: 10.1039/C2SC21914J
Citation: Chem. Sci., 2013,4, 1105-1110
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    Stereoselective intramolecular cyclopropanation through catalytic olefin activation

    X. Huang, S. Klimczyk, L. F. Veiros and N. Maulide, Chem. Sci., 2013, 4, 1105
    DOI: 10.1039/C2SC21914J

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