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Issue 33, 2013
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Tandem semi-hydrogenation/isomerization of propargyl alcohols to saturated carbonyl analogues by dodecanethiolate-capped palladium nanoparticle catalysts

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Abstract

The efficient one-pot conversion of propargyl alcohols to their saturated carbonyl analogues is carried out for the first time using metal nanoparticle catalysts, dodecanethiolate-capped Pd nanoparticles. Kinetic studies reveal that the reaction progresses through a semi-hydrogenation intermediate (allyl alcohols) followed by isomerization to carbonyls.

Graphical abstract: Tandem semi-hydrogenation/isomerization of propargyl alcohols to saturated carbonyl analogues by dodecanethiolate-capped palladium nanoparticle catalysts

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Publication details

The article was received on 29 Apr 2013, accepted on 07 Jun 2013 and first published on 07 Jun 2013


Article type: Communication
DOI: 10.1039/C3RA42119H
Citation: RSC Adv., 2013,3, 13642-13645
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    Tandem semi-hydrogenation/isomerization of propargyl alcohols to saturated carbonyl analogues by dodecanethiolate-capped palladium nanoparticle catalysts

    D. J. Gavia, J. Koeppen, E. Sadeghmoghaddam and Y. Shon, RSC Adv., 2013, 3, 13642
    DOI: 10.1039/C3RA42119H

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