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Issue 8, 2013
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A conversion of aromatic thiocyanates into sulfothioates: new synthetic route to aromatic Bunte salts

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Abstract

A new synthetic route leading to polysubstituted S-aryl sulfothioates, aromatic Bunte salts, is reported. Treatment of polysubstituted aromatic thiocyanates with sodium sulfite in aqueous DMF at room temperature affords polysubstituted S-(het)aryl sulfothioates. The novel transformation tolerates presence of a wide range of functional groups.

Graphical abstract: A conversion of aromatic thiocyanates into sulfothioates: new synthetic route to aromatic Bunte salts

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Publication details

The article was received on 29 Aug 2012, accepted on 16 Dec 2012 and first published on 18 Dec 2012


Article type: Paper
DOI: 10.1039/C2RA21975A
Citation: RSC Adv., 2013,3, 2650-2654
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    A conversion of aromatic thiocyanates into sulfothioates: new synthetic route to aromatic Bunte salts

    P. Jansa, L. Čechová, M. Dračínský and Z. Janeba, RSC Adv., 2013, 3, 2650
    DOI: 10.1039/C2RA21975A

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