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Issue 43, 2013
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Correlating electronic structures to electrochemiluminescence of cationic Ir complexes

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Abstract

Electrochemiluminescence (ECL) of heteroleptic cationic iridium complexes is correlated to their structures in order to get insight into tuning their emission wavelength and intensity. While the installation of fluorine and tert-butyl substituents on the ligands increases the electrochemical gap and promotes blue shifts in ECL emission, it reduces ECL efficiencies.

Graphical abstract: Correlating electronic structures to electrochemiluminescence of cationic Ir complexes

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Publication details

The article was received on 22 Jun 2013, accepted on 03 Sep 2013 and first published on 05 Sep 2013


Article type: Communication
DOI: 10.1039/C3RA43134G
Citation: RSC Adv., 2013,3, 19961-19964
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    Correlating electronic structures to electrochemiluminescence of cationic Ir complexes

    K. N. Swanick, S. Ladouceur, E. Zysman-Colman and Z. Ding, RSC Adv., 2013, 3, 19961
    DOI: 10.1039/C3RA43134G

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