Issue 43, 2013

Correlating electronic structures to electrochemiluminescence of cationic Ir complexes

Abstract

Electrochemiluminescence (ECL) of heteroleptic cationic iridium complexes is correlated to their structures in order to get insight into tuning their emission wavelength and intensity. While the installation of fluorine and tert-butyl substituents on the ligands increases the electrochemical gap and promotes blue shifts in ECL emission, it reduces ECL efficiencies.

Graphical abstract: Correlating electronic structures to electrochemiluminescence of cationic Ir complexes

Supplementary files

Article information

Article type
Communication
Submitted
22 Jun 2013
Accepted
03 Sep 2013
First published
05 Sep 2013

RSC Adv., 2013,3, 19961-19964

Correlating electronic structures to electrochemiluminescence of cationic Ir complexes

K. N. Swanick, S. Ladouceur, E. Zysman-Colman and Z. Ding, RSC Adv., 2013, 3, 19961 DOI: 10.1039/C3RA43134G

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