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Issue 47, 2013
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Aromatic C–H silylation of arenes with 1-hydrosilatrane catalyzed by an iridium(I)/2,9-dimethylphenanthroline (dmphen) complex

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Abstract

Aromatic C–H silylation of neat arenes with 1-hydrosilatrane was found to be efficiently catalyzed by iridium catalysts composed of 1/2[Ir(OMe)(cod)]2 and 2,9-dimethyl-1,10-phenanthroline at 120 °C to afford the corresponding silylated products in high yields. The silylated products can be used for the Hiyama cross-coupling reaction.

Graphical abstract: Aromatic C–H silylation of arenes with 1-hydrosilatrane catalyzed by an iridium(i)/2,9-dimethylphenanthroline (dmphen) complex

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Publication details

The article was received on 08 Aug 2013, accepted on 12 Oct 2013 and first published on 15 Oct 2013


Article type: Communication
DOI: 10.1039/C3OB41623B
Citation: Org. Biomol. Chem., 2013,11, 8162-8165
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    Aromatic C–H silylation of arenes with 1-hydrosilatrane catalyzed by an iridium(I)/2,9-dimethylphenanthroline (dmphen) complex

    T. Ishiyama, T. Saiki, E. Kishida, I. Sasaki, H. Ito and N. Miyaura, Org. Biomol. Chem., 2013, 11, 8162
    DOI: 10.1039/C3OB41623B

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