Issue 33, 2013

Meta-arylation of calixarenes using organomercurial chemistry

Abstract

A direct mercuration reaction combined with a subsequent Pd-catalyzed arylation was used to introduce the aryl moiety into the meta position of the calix[4]arene skeleton. The application of organomercurial intermediates thus allows the straightforward formation of meta-aryl-substituted derivatives representing a unique substitution pattern in calixarene chemistry.

Graphical abstract: Meta-arylation of calixarenes using organomercurial chemistry

Supplementary files

Article information

Article type
Paper
Submitted
24 May 2013
Accepted
02 Jul 2013
First published
02 Jul 2013

Org. Biomol. Chem., 2013,11, 5528-5534

Meta-arylation of calixarenes using organomercurial chemistry

P. Slavík, K. Flídrová, H. Dvořáková, V. Eigner and P. Lhoták, Org. Biomol. Chem., 2013, 11, 5528 DOI: 10.1039/C3OB41085D

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