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Issue 26, 2013
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Convenient in situ generation of various dichlorinating agents from oxone and chloride: diastereoselective dichlorination of allylic and homoallylic alcohol derivatives

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Abstract

A safe and convenient protocol was developed for in situ generation of various dichlorinating agents (cf. Cl2, NCl3, Et4NCl3, ArICl2) from oxone and chloride. The synthetic utility of this protocol was demonstrated by diastereoselective dichlorination of a series of allylic and homoallylic alcohol derivatives with excellent yields and diastereoselectivity.

Graphical abstract: Convenient in situ generation of various dichlorinating agents from oxone and chloride: diastereoselective dichlorination of allylic and homoallylic alcohol derivatives

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Publication details

The article was received on 04 Apr 2013, accepted on 13 May 2013 and first published on 14 May 2013


Article type: Communication
DOI: 10.1039/C3OB40670A
Citation: Org. Biomol. Chem., 2013,11, 4312-4315
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    Convenient in situ generation of various dichlorinating agents from oxone and chloride: diastereoselective dichlorination of allylic and homoallylic alcohol derivatives

    J. Ren and R. Tong, Org. Biomol. Chem., 2013, 11, 4312
    DOI: 10.1039/C3OB40670A

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