Regio- and chemoselective palladium-catalyzed benzylallylation of activated olefins: the remarkable effect of palladium nanoparticles

Xuan Zhang; Xiujuan Feng; Xiaoqiang Yu; Ren He; Ming Bao

doi:10.1039/C3OB40487K

Regio- and chemoselective palladium-catalyzed benzylallylation of activated olefins: the remarkable effect of palladium nanoparticles

Xuan Zhang,^a Xiujuan Feng,*^a Xiaoqiang Yu,^a Ren He^a and Ming Bao*^a

* Corresponding authors

^a State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023, China
E-mail: fengxiujuan@dlut.edu.cn, mingbao@dlut.edu.cn
Fax: +86-0411-84986180
Tel: +86-0411-84986181

Abstract

The palladium-catalyzed three-component reactions of benzyl halides, activated olefins, and allyltributylstannane were successfully conducted to produce the corresponding benzylallylation products in satisfactory to high yields. The benzylallylation reaction proceeded smoothly under mild conditions in the presence of palladium nanoparticles in tetrahydrofuran.

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Publication details

The article was received on 09 Mar 2013, accepted on 16 Apr 2013 and first published on 16 Apr 2013

Article type: Paper

DOI: 10.1039/C3OB40487K

Citation: Org. Biomol. Chem., 2013,11, 4016-4024

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Regio- and chemoselective palladium-catalyzed benzylallylation of activated olefins: the remarkable effect of palladium nanoparticles

X. Zhang, X. Feng, X. Yu, R. He and M. Bao, Org. Biomol. Chem., 2013, 11, 4016
DOI: 10.1039/C3OB40487K
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Organic & Biomolecular Chemistry

Regio- and chemoselective palladium-catalyzed benzylallylation of activated olefins: the remarkable effect of palladium nanoparticles

Abstract

Supplementary files

Publication details

Regio- and chemoselective palladium-catalyzed benzylallylation of activated olefins: the remarkable effect of palladium nanoparticles

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