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Issue 17, 2013
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Copper-catalyzed aromatic C–H bond halogenation with lithium halides under aerobic conditions

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Abstract

A concise and practical Cu-catalyzed protocol for the preparation of chloro- and bromoarenes via C–H bond activation has been developed. The advantages of this strategy are the employment of cheap Cu(NO3)2·3H2O, LiX and O2, and its compatibility with both electron-donating and electron-withdrawing substituents on aryl rings.

Graphical abstract: Copper-catalyzed aromatic C–H bond halogenation with lithium halides under aerobic conditions

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Publication details

The article was received on 28 Jan 2013, accepted on 15 Feb 2013 and first published on 20 Feb 2013


Article type: Communication
DOI: 10.1039/C3OB40185E
Citation: Org. Biomol. Chem., 2013,11, 2756-2760
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    Copper-catalyzed aromatic C–H bond halogenation with lithium halides under aerobic conditions

    S. Mo, Y. Zhu and Z. Shen, Org. Biomol. Chem., 2013, 11, 2756
    DOI: 10.1039/C3OB40185E

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