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Issue 10, 2013
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Design and synthesis of stable α-diazo-β-oxo sulfoxides

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Abstract

Diazo transfer adjacent to a sulfoxide moiety to provide stable, isolable α-diazo-β-oxo sulfoxides has been achieved. Use of monocyclic and bicyclic sulfoxide precursors is critical in enabling isolation of stable derivatives, through introduction of conformational constraint, while acyclic α-diazo-β-oxo sulfoxides are too labile to isolate and characterize.

Graphical abstract: Design and synthesis of stable α-diazo-β-oxo sulfoxides

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Publication details

The article was received on 06 Jul 2012, accepted on 09 Jan 2013 and first published on 10 Jan 2013


Article type: Paper
DOI: 10.1039/C3OB27061K
Citation: Org. Biomol. Chem., 2013,11, 1706-1725
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    Design and synthesis of stable α-diazo-β-oxo sulfoxides

    S. G. Collins, O. C. M. O'Sullivan, P. G. Kelleher and A. R. Maguire, Org. Biomol. Chem., 2013, 11, 1706
    DOI: 10.1039/C3OB27061K

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