The biosynthesis of tricho-acorenol in Trichoderma harzianum was investigated by feeding stereospecifically deuterated mevalonolactone isotopomers, followed by a detailed GC/MS analysis of the incorporation of labelling. The results establish a highly stereospecific hydride migration and antarafacial attack of water in the terminal step towards tricho-acorenol.
C. A. Citron and J. S. Dickschat, Org. Biomol. Chem., 2013, 11, 7447 DOI: 10.1039/C3OB41755G
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