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Bridgehead enolate or bridgehead organolithium? DFT calculations provide insights into a difficult bridgehead substitution reaction in the synthesis of the polycyclic polyprenylated acylphloroglucinol (PPAP) nemorosone

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School of Chemistry, The University of Nottingham, University Park, Nottingham, UK
School of Chemistry, University of Birmingham, Edgbaston, Birmingham, UK
Org. Biomol. Chem., 2013,11, 8458-8462

DOI: 10.1039/C3OB41064A
Received 22 May 2013, Accepted 24 Oct 2013
First published online 28 Oct 2013
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