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Issue 27, 2013
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Organocatalytic functionalization of heteroaromatic N-oxides with C-nucleophiles using in situ generated onium amide bases

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Abstract

Organocatalytic functionalization of heteroaromatic N-oxides was investigated using in situ generated onium amide bases, and C-nucleophiles were efficiently introduced by the sequential addition–elimination reaction under metal-free conditions, affording 2-substituted nitrogen heteroaromatics generally in good to high yields.

Graphical abstract: Organocatalytic functionalization of heteroaromatic N-oxides with C-nucleophiles using in situ generated onium amide bases

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Publication details

The article was received on 18 Apr 2013, accepted on 28 May 2013 and first published on 29 May 2013


Article type: Communication
DOI: 10.1039/C3OB40782A
Citation: Org. Biomol. Chem., 2013,11, 4438-4441
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    Organocatalytic functionalization of heteroaromatic N-oxides with C-nucleophiles using in situ generated onium amide bases

    K. Inamoto, Y. Araki, S. Kikkawa, M. Yonemoto, Y. Tanaka and Y. Kondo, Org. Biomol. Chem., 2013, 11, 4438
    DOI: 10.1039/C3OB40782A

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