Department of Chemistry and Biology and the Centre for Urban Energy (CUE), Ryerson University, 350 Victoria St., Toronto, Canada
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Org. Biomol. Chem., 2013,11, 3756-3760
31 Jan 2013,
24 Apr 2013
First published online
25 Apr 2013
The syntheses and physicochemical properties for a series of 2,6-disubstituted-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dyes are reported. The use of chromophores or redox active species as π-spacers, such as BODIPY, requires the inclusion of a sufficiently conjugated donor in order to achieve appropriate charge separation upon photoexcitation. The information derived from this study offers guiding principles for incorporating strongly absorbing, non-innocent π-spacers in organic dye design.
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Organic & Biomolecular Chemistry
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