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Issue 10, 2013
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Tetrabutylammonium iodide catalyzed allylic sulfonylation of Baylis–Hillman acetates with sulfonylhydrazides in water

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Abstract

A tetrabutylammonium iodide catalyzed method for the synthesis of allyl aryl sulfone derivatives with Baylis–Hillman acetates and sulfonylhydrazides using tert-butyl hydroperoxide as an oxidation agent in water has been developed. In this process, the group eliminated from the sulfonyl precursor is molecular nitrogen.

Graphical abstract: Tetrabutylammonium iodide catalyzed allylic sulfonylation of Baylis–Hillman acetates with sulfonylhydrazides in water

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Publication details

The article was received on 30 Nov 2012, accepted on 18 Jan 2013 and first published on 22 Jan 2013


Article type: Paper
DOI: 10.1039/C3OB27329F
Citation: Org. Biomol. Chem., 2013,11, 1739-1742
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    Tetrabutylammonium iodide catalyzed allylic sulfonylation of Baylis–Hillman acetates with sulfonylhydrazides in water

    X. Li, X. Xu and Y. Tang, Org. Biomol. Chem., 2013, 11, 1739
    DOI: 10.1039/C3OB27329F

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