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Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan 430079, P. R. China
; Tel: +86 027 6786 7773
Org. Biomol. Chem., 2013,11, 1226-1233
17 Oct 2012,
17 Dec 2012
First published online
19 Dec 2012
A highly efficient method for the direct synthesis of α-iodoketals from methyl ketones has been developed via sustainable integration of orthogonal tandem catalytic reactions: copper(II) oxide catalyzed iodination reaction and the subsequent excess or regenerated iodine catalyzed regioselective ketalization reaction.
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Organic & Biomolecular Chemistry
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