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Issue 8, 2013
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A stochastic principle behind polar properties of condensed molecular matter

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Abstract

A statistical mechanics view leads to the conclusion that polar molecules allowed to populate a degree of freedom for orientational disorder in a condensed phase thermalize into a bi-polar state featuring zero net polarity. In cases of orientational disorder polar order of condensed molecular matter can only exist in corresponding sectors of opposite average polarities. Channel type inclusion compounds, single component molecular crystals, solid solutions, optically anomalous crystals, inorganic ionic crystals, biomimetic crystals and biological tissues investigated by scanning pyroelectric and phase sensitive second harmonic generation microscopy all showed domains of opposite polarities in their final grown state. For reported polar molecular crystal structures it is assumed that kinetic hindrance along one direction of the polar axis is preventing the formation of a bi-polar state, thus allowing for a kinetically controlled mono-domain state. In this review we summarize theoretical and experimental findings leading to far reaching conclusions on the polar state of solid molecular matter. “… no stationary stateof a system has an electrical dipole moment.” P. W. Anderson, Science, 1972, 177, 393.

Graphical abstract: A stochastic principle behind polar properties of condensed molecular matter

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Publication details

The article was received on 16 Oct 2012, accepted on 11 Mar 2013 and first published on 18 Mar 2013


Article type: Focus
DOI: 10.1039/C3NJ40935J
Citation: New J. Chem., 2013,37, 2229-2235
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    A stochastic principle behind polar properties of condensed molecular matter

    J. Hulliger, T. Wüst, K. Brahimi, M. Burgener and H. Aboulfadl, New J. Chem., 2013, 37, 2229
    DOI: 10.1039/C3NJ40935J

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