Synthesis of new ω-amino- and ω-azidoalkyl carboranes

Marina Yu. Stogniy; Igor B. Sivaev; Ivan A. Godovikov; Zoya A. Starikova; Vladimir I. Bregadze; Shicheng Qi

doi:10.1039/C3NJ00677H

Synthesis of new ω-amino- and ω-azidoalkyl carboranes

Marina Yu. Stogniy,^a Igor B. Sivaev,*^a Ivan A. Godovikov,^a Zoya A. Starikova,^a Vladimir I. Bregadze^a and Shicheng Qi^b

Author affiliations

* Corresponding authors

^a A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov Str. 28, Moscow, Russia
E-mail: sivaev@ineos.ac.ru

^b College of Materials, Science and Engineering, Beijing University of Chemical Technology, Beijing, China

Abstract

Novel carboranyl amines [7-NH₂(CH₂)_nS-7,8-C₂B₉H₁₁]⁻ were synthesized by alkylation of 1-mercapto-ortho-carborane with ω-bromoalkylphthalimides followed by removal of the protecting group with hydrazine. closo-Carboranyl azides 1-N₃(CH₂)_nS-1,2-C₂B₁₀H₁₁ were prepared by the reaction of the corresponding carboranyl alcohol/iodide with sodium azide and converted to the water soluble nido-form [7-N₃(CH₂)_nS-7,8-C₂B₉H₁₁]⁻ with ammonium formate in refluxing methanol.

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Publication details

The article was received on 22 Jun 2013, accepted on 02 Oct 2013 and first published on 03 Oct 2013

Article type: Letter

DOI: 10.1039/C3NJ00677H

Citation: New J. Chem., 2013,37, 3865-3868

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Synthesis of new ω-amino- and ω-azidoalkyl carboranes

M. Yu. Stogniy, I. B. Sivaev, I. A. Godovikov, Z. A. Starikova, V. I. Bregadze and S. Qi, New J. Chem., 2013, 37, 3865
DOI: 10.1039/C3NJ00677H
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New Journal of Chemistry

Synthesis of new ω-amino- and ω-azidoalkyl carboranes

Abstract

Supplementary files

Publication details

Synthesis of new ω-amino- and ω-azidoalkyl carboranes

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