Issue 11, 2013
From the journal:

New Journal of Chemistry

Formylazido substituted nitro hexaazaisowurtzitane – synthesis, characterization and energetic properties†

Kai Dong,a   Yuan Wang,a   Xu-Bin Gong,a   Jing Zhang,a   Cheng-Hui Sun*a  and  Si-Ping Pang*ab  

* Corresponding authors

a School of Materials Science & Engineering, Beijing Institute of Technology, Beijing, P. R. China
E-mail: sunch@bit.edu.cn, pangsp@bit.edu.cn
Fax: +86-010-68918049

b State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, 5 South Zhongguancun Street, Haidian District, Beijing 100081, P. R. China
E-mail: pangsp@bit.edu.cn
Fax: +86-010-68913038
Tel: +86-010-68913038

Abstract

Formyl azido substituted nitro hexaazaisowurtzitane derivatives, 2,4,6,8,12-pentanitro-10-formylazido-hexaazaisowurtzitane and 2,6,8,12-tetranitro-4,10-diformylazido-hexaazaisowurtzitane, have been synthesized and well characterized by IR and NMR (1H, 13C) spectroscopy, mass spectroscopy (MS), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and single-crystal X-ray diffraction. Their key properties such as melting points and decomposition temperatures, densities, dissociation energy of bonds (BDE), electrostatic potential (ESP), impact sensitivity (IS), detonation pressures (P) and velocities (D) were measured or calculated, which indicated an excellent combination of admirable detonation performance and stability as potential energetic compounds.

Graphical abstract: Formyl azido substituted nitro hexaazaisowurtzitane – synthesis, characterization and energetic properties

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Article information

DOI
https://doi.org/10.1039/C3NJ00532A
Article type
Paper
Submitted
18 May 2013
Accepted
19 Aug 2013
First published
20 Aug 2013

New J. Chem., 2013,37, 3685-3691

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Formyl azido substituted nitro hexaazaisowurtzitane – synthesis, characterization and energetic properties

K. Dong, Y. Wang, X. Gong, J. Zhang, C. Sun and S. Pang, New J. Chem., 2013, 37, 3685 DOI: 10.1039/C3NJ00532A

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