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Issue 8, 2013
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Bromine kinetic isotope effects: insight into Grignard reagent formation

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Abstract

The study focuses on the determination of bromine kinetic isotope effects (Br-KIEs) on Grignard reagent formation applying compound specific bromine isotope analysis. Clear difference between the Br-KIE values for aromatic and aliphatic bromides was observed. The measured Br-KIE values were found to be in a good agreement with the theoretical predictions.

Graphical abstract: Bromine kinetic isotope effects: insight into Grignard reagent formation

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Publication details

The article was received on 20 Feb 2013, accepted on 25 Mar 2013 and first published on 26 Mar 2013


Article type: Letter
DOI: 10.1039/C3NJ00197K
Citation: New J. Chem., 2013,37, 2241-2244
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    Bromine kinetic isotope effects: insight into Grignard reagent formation

    L. Szatkowski, A. Dybala-Defratyka, C. Batarseh, J. Blum, L. Halicz and F. Gelman, New J. Chem., 2013, 37, 2241
    DOI: 10.1039/C3NJ00197K

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