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Issue 11, 2013
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Ammoxidation of allyl alcohol – a sustainable route to acrylonitrile

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Abstract

The ammoxidation of allyl alcohol was demonstrated over antimony–iron oxide catalysts with a Sb/Fe ratio of 0.6 and 1. Both catalysts showed high performance with 83 and 84% yield of acrylonitrile, respectively, whereby the main difference was found in the initial performance. This was ascribed to the in-operando formation of the SbFeO4 mixed oxide on the catalyst surface under reaction conditions, as proven by XPS analysis.

Graphical abstract: Ammoxidation of allyl alcohol – a sustainable route to acrylonitrile

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Publication details

The article was received on 07 Jun 2013, accepted on 12 Aug 2013 and first published on 12 Aug 2013


Article type: Communication
DOI: 10.1039/C3GC41089G
Citation: Green Chem., 2013,15, 3015-3019
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    Ammoxidation of allyl alcohol – a sustainable route to acrylonitrile

    C. Guillon, C. Liebig, S. Paul, A. Mamede, W. F. Hölderich, F. Dumeignil and B. Katryniok, Green Chem., 2013, 15, 3015
    DOI: 10.1039/C3GC41089G

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