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Issue 3, 2014
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A mechanochemical strategy for oxidative addition: remarkable yields and stereoselectivity in the halogenation of organometallic Re(I) complexes

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Abstract

A simple solvent-free mechanochemical procedure enables rapid and high-yielding oxidative halogenation of model organometallic Re(I) compounds with excellent and tunable stereoselectivity, demonstrating how mechanochemistry can advance and simplify fundamental organometallic transformations.

Graphical abstract: A mechanochemical strategy for oxidative addition: remarkable yields and stereoselectivity in the halogenation of organometallic Re(i) complexes

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Publication details

The article was received on 10 Oct 2013, accepted on 07 Nov 2013 and first published on 08 Nov 2013


Article type: Communication
DOI: 10.1039/C3GC42104J
Citation: Green Chem., 2014,16, 1087-1092
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    A mechanochemical strategy for oxidative addition: remarkable yields and stereoselectivity in the halogenation of organometallic Re(I) complexes

    J. G. Hernández, N. A. J. Macdonald, C. Mottillo, I. S. Butler and T. Friščić, Green Chem., 2014, 16, 1087
    DOI: 10.1039/C3GC42104J

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