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Issue 31, 2013
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Layer-by-layer aqueous rapid synthesis of ZIF-8 films on a reactive surface

Koji Kida,a  Kosuke Fujita,a  Tomoko Shimada,a  Shunsuke Tanaka*ab  and  Yoshikazu Miyakeab 
Author affiliations

* Corresponding authors

a Department of Chemical, Energy and Environmental Engineering, Faculty of Environmental and Urban Engineering, Kansai University, 3-3-35 Yamate-cho, Suita-shi, Osaka 564-8680, Japan
E-mail: shun_tnk@kansai-u.ac.jp
Fax: +81-6-6388-8869
Tel: +81-6-6368-0851

b Organization for Research and Development of Innovation Science and Technology (ORDIST), Kansai University, Japan

Abstract

The synthesis of zeolitic imidazolate framework-8 (ZIF-8) films in an aqueous system was achieved. ZIF-8 films with controllable thickness were successfully grown on a modified substrate at room temperature. The 3-(2-imidazolin-1-yl)propyltriethoxysilane (IPTES) was used to first form a pseudo-surface of ZIF-8 on a glass substrate, followed by layer-by-layer growth. The film thickness of ZIF-8 was controlled within the range from 220 to 640 nm per growth cycle by changing the reactivity of the zinc source. Notably, the use of a preorganized zinc source led to drastic changes in the formation rate of ZIF-8. The use of a low-reactivity growth solution containing zinc acetate thus allowed the preparation of dense ZIF-8 films.

Graphical abstract: Layer-by-layer aqueous rapid synthesis of ZIF-8 films on a reactive surface

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Publication details

The article was received on 01 May 2013, accepted on 30 May 2013 and first published on 03 Jun 2013


Article type: Paper
DOI: 10.1039/C3DT51135A
Citation: Dalton Trans., 2013,42, 11128-11135
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    Layer-by-layer aqueous rapid synthesis of ZIF-8 films on a reactive surface

    K. Kida, K. Fujita, T. Shimada, S. Tanaka and Y. Miyake, Dalton Trans., 2013, 42, 11128
    DOI: 10.1039/C3DT51135A

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