Issue 32, 2013
From the journal:

Dalton Transactions

Quick and selective synthesis of Li6[α-P2W18O62]·28H2O soluble in various organic solvents†

Chisato Kato,a   Sadafumi Nishihara,*abc   Ryo Tsunashima,d   Yoko Tatewaki,e   Shuji Okada,e   Xiao-Ming Ren,fg   Katsuya Inoue,*ab   De-Liang Longc  and  Leroy Croninc  

* Corresponding authors

a Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526, Japan
E-mail: snishi@hiroshima-u.ac.jp
Fax: +81 82 424 7418

b Institute for Advanced Materials Research, Hiroshima University, Higashi-Hiroshima 739-8530, Japan

c WestCHEM, School of Chemistry, The University of Glasgow, Glasgow G12 8QQ, UK

d Graduate School of Science and Engineering, Yamaguchi University, Yamaguchi, Japan

e Graduate School of Science and Engineering, Yamagata University, Yonezawa 992-8510, Japan

f State Key Laboratory of Materials-Oriented Chemical Engineering and College of Science, Nanjing University of Technology, Nanjing 210009, China

g Coordination Chemistry Institute and State Key Laboratory, Nanjing University, Nanjing 210093, China

Abstract

Herein we report the synthesis of α-Dawson type POM, Li6[α-P2W18O62]·28H2O, directly from the use of Li2WO4 as the tungstate source. The salt obtained was soluble not only in water but also in a range of polar and non-polar organic solvents, such as benzene.

Graphical abstract: Quick and selective synthesis of Li6[α-P2W18O62]·28H2O soluble in various organic solvents

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Article information

DOI
https://doi.org/10.1039/C3DT51120K
Article type
Communication
Submitted
29 Apr 2013
Accepted
17 Jun 2013
First published
08 Jul 2013

Dalton Trans., 2013,42, 11363-11366

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Quick and selective synthesis of Li6[α-P2W18O62]·28H2O soluble in various organic solvents

C. Kato, S. Nishihara, R. Tsunashima, Y. Tatewaki, S. Okada, X. Ren, K. Inoue, D. Long and L. Cronin, Dalton Trans., 2013, 42, 11363 DOI: 10.1039/C3DT51120K

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