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Issue 32, 2013
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Quick and selective synthesis of Li6[α-P2W18O62]·28H2O soluble in various organic solvents

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Abstract

Herein we report the synthesis of α-Dawson type POM, Li6[α-P2W18O62]·28H2O, directly from the use of Li2WO4 as the tungstate source. The salt obtained was soluble not only in water but also in a range of polar and non-polar organic solvents, such as benzene.

Graphical abstract: Quick and selective synthesis of Li6[α-P2W18O62]·28H2O soluble in various organic solvents

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Publication details

The article was received on 29 Apr 2013, accepted on 17 Jun 2013 and first published on 08 Jul 2013


Article type: Communication
DOI: 10.1039/C3DT51120K
Citation: Dalton Trans., 2013,42, 11363-11366
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    Quick and selective synthesis of Li6[α-P2W18O62]·28H2O soluble in various organic solvents

    C. Kato, S. Nishihara, R. Tsunashima, Y. Tatewaki, S. Okada, X. Ren, K. Inoue, D. Long and L. Cronin, Dalton Trans., 2013, 42, 11363
    DOI: 10.1039/C3DT51120K

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